Worn by: Paul Stassino as Angelo Palazzi
Reference: Breitling Navitimer
Brand: Breitling
While Sean Connery, who played Bond in Thunderball, wore a Breitling Top Time, Paul Stassino, who plays Angelo Palazzi, wore a Breitling Navitimer 806. His piece had both a black dial and subdials. The watch features a day and date complication as well. The Navitimer 806 was a sophisticated choice for the character in this 1965 James Bond film.

Source: https://www.wristenthusiast.com/latest/2022/7/13/breitling-watches-in-movies-and-tv
Worn by: Sean Connery as James Bond
Reference: Breitling Top Time
Brand: Breitling
James Bond himself, Sean Connery, wore a Breitling Top Time in the 1965 Bond film Thunderball. This Breitling was in fact the only watch that Connery wore besides his signature Rolex Submariner throughout his tenure as Bond. Connery's screen-worn Top Time was auctioned off in 2013 by Christie's and sold for $160,175 USD, demonstrating the collectible value of Bond-worn timepieces.

Source: https://www.wristenthusiast.com/latest/2022/7/13/breitling-watches-in-movies-and-tv